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what can we do to make it super reliable?
Carry spares of likely-to-fail parts, and tools to replace them. That way you'll never need to.
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Ignition System - What is the simplest and most reliable ignition system? Best distributor?
See
HEI upgrade (and note the small size of the HEI module; makes it easy to carry a spare)
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Fuel Delivery System - What is the simplest and most reliable fuel delivery system?
There is more than one correct answer to this. What's your budget for putting together a fuel system? How far from stock are you willing to deviate? What regulations (emissions tests?) apply to your vehicle where you live now…and where you're likely to live in future?
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Other weak links such as distributor gear and oil pump drive system.
Neither of these is a weak link.
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Vacuum Leaks - What can I do to help prevent and guard against vacuum leaks
Don't create them in the first place, and use high-quality fittings and hose.
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One reason that I note "simplest" is because with more complexity you have more things to break. For example, fuel injection may be more reliable in general, but if the ECU dies, you are dead in the water. Whereas with a carburetor it may run less than ideal and need more tuning, but there are much less things to break.
This is a few different kinds of wrong. For one thing, a fuel injection system is
much simpler than a carburetor. EFI has fewer parts, and the parts are much less complex; there's a lot less to break. ECUs mostly don't die, but if you're consumed with fear of the extremely unlikely, well…carry a spare ECU.
Carburetors, on the other hand, are
full of finicky parts just waiting to break or fail or otherwise stop your car. Combine the difficult availability of good carburetors at this late date; the near-extinction of apposite repair knowledge in today's world, and the carburetor-hostile formulation of modern gasoline, and then consider that one of the big reasons why gas stations have food marts instead of service bays now is that fuel injection doesn't crap out like carburetors did, and…well…kinda…time to rethink the idea that a carburetor is more reliable. It isn't.
On the other-other hand, there's no off-the-shelf/drop-on Slant-6 fuel injection system, so you'd have to be prepared to do some amount of roll-your-owning. If not, then the right answer for your particular case might be to very carefully choose a carburetor and live with it.
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