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I've heard that silicone brake fluid can cause corrosion problems because it traps water in the lower portions of your brake system, instead of absorbing water like DOT-3 does.
Does anyone have EVIDENCE and PROOF of this phenomena? Come on, let's see it!!
Yep, I've seen it. Nope, it's not a rumor. Yep, it's ugly, sudden, usually catastrophic and virtually impossible to predict/detect until it happens. Nope, don't have pictures.
Silicone fluid isn't necessarily better, and even if you believe it is, it's not a throw-it-in-and-forget-about-it-forever deal.
Here's the thing: no seal is perfect. Moisture
can, does, and will get into the brake hydraulic system due to humidity gradients, temperature gradients and pressure gradients across the seals. How much moisture gets in is highly variable, depending on ambient moisture (more in Portland than in Phoenix!), system heat levels reached, duration of just sitting around, owner maintenance practices, and so forth.
When moisture enters a system filled with regular brake fluid (DOT 3, 4 or 5.1), the fluid absorbs the water. This disperses the water throughout a relatively large area of the system. It's never good to have moisture in the brake hydraulics, but this dispersal means that a relatively large amount of water has to accumulate in the system, and remain unflushed for a long time, before corrosive attack becomes a possibility worth worrying about.
When moisture enters a system filled with non-hygroscopic brake fluid (DOT 5 silicone), it is not dispersed or absorbed. It remains in a cohesive blob, which tends to get mechanically moved (swept by brake fluid motion, pulled by gravity) to the lowest points in the system. It remains there, highly localized and much more concentrated than if the brake fluid had dispersed it, and—depending on the materials it happens to be contacting—can begin to corrode important piece of your brake system from the inside out.
That's the way it works. Now, how much of a problem/risk is it? Totally depends on how you maintain the system. With any/all fluids, as long as the system is flushed and refilled every so often (every few years) you shouldn't have any brake hydraulic system problems.
The other nuisance with silicone fluid is that it is much, much more difficult to get a firm pedal with it, for its consistency is such that it traps air in tiny bubbles that are very slow to rise to the surface and pop. That's why the silicone fluid container warns you not to drop it, shake it, etc. Good practice is to pour the fluid against the sloping sidewall of a funnel rather than directly into the master cylinder—this gives the bubbles a good shot at popping.
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